Wednesday, January 29, 2020

Investigating the Effects of Surface Area on the Rate of Reaction Essay Example for Free

Investigating the Effects of Surface Area on the Rate of Reaction Essay Aim: To study the effects of changing the surface area on the rate of a chemical reaction Hypothesis: This hypothesis is based on the Collision Theory, where in order to react, the two particles involved must: 1. Collide with each other 2. The collision must be energetic enough to overcome the activation energy of the reaction 3. The collision must bring the reactive parts of the molecule into contact the correct way – they must collide with appropriate geometry (the reactive parts) Considering that the surface area of a particle is a factor that mainly affects the collision rate of particles, it would be safe to assume that as the surface area increases, the reaction rate increases. The graph should turn out to be something like this: 1. the reaction is the fastest at the start 2. The reaction is slowing down here 3. No more product is formed Amount of product Time Variables: Variable Factor What is manipulated Dependent Time The time it takes for the reaction to complete depends on the surface area of the compounds being used, because it determines the rate in which the reaction will occur. Independent Volume of the gas collected (H2, CO2) The amount of gas collected for each experiment will depend on the Controlled 1. Mass of Calcium Carbonate (both marble chips and powdered form) 2. Mass of Magnesium (both ribbon and powder) 3. Volume of Hydrochloric Acid 4. Apparatus Used 1. The masses of the substances utilized will remain constantly fixed during the experiment 2. 50 cm3 of HCl will be used for every trial – 550 cm3 in total 3. The apparatus used will remain the same throughout the whole experiment Chemical Reactions: Mg + 2HCl → MgCl2 + H2 1. Magnesium ribbon 2. Hydrogen Gas will be the gas collected 1. 3 Trials will take place 1. Mass of Magnesium ribbon in: 1. Trial 1: 0.064 grams 2. Trial 2: 0.063 grams 3. Trial 3: 0.065 grams CaCO3 + 2HCl → CaCl2 + H2O + CO2 1. Marble Chips 2. Carbon Dioxide will be the gas collected 1. 2 Trials will take place 1. Mass of Marble Chips in: 1. Trial 1: 3.998 grams 2. Trial 2: 3.988 grams Na2CO3 + 2HCl → 2NaCl + H2O + CO2 1. Sodium Carbonate (Powdered) 2. Carbon Dioxide will be the gas collected 1. 2 Trials will take place 1. Mass of Sodium Carbonate 1. Trial 1: 0.504 grams 2. Trial 2: 0.505 grams Apparatus: 1. Eye-Protection – 1 pair of Safety Glasses 2. 1 pair of Scissors 3. 1 Electronic Scale 4. 1 Conical Flask (100cm3) 5. 1 Single-holed rubber bung and delivery tube to fit conical flask 6. 1 Measuring cylinder (100cm3) 7. Stopwatch Chemicals: 1. 12cm of Magnesium Ribbon 2. 550 cm3 of Hydrochloric Acid 3. Marble Chips 4. Sodium Carbonate (Powdered) Method: 1. Set up apparatus as shown 2. Fill the conical flask with 50cm3 of HCl 3. Insert the end of the syringe into the hole on top of the stopper 4. Add the magnesium ribbon 5. Seal the flask with a rubber stopper as quickly as you can, at the same time have someone else present to start the stop watch once the magnesium ribbon has been added to the hydrochloric acid 6. As the reaction takes place, note down the time it takes for the gas collected to reach a multiple of 5 (i.e. 5mL, 10mL †¦.50,55,60,65 etc) 7. Keep measuring until the reaction has stopped, or you are unable to measure anymore 8. Repeat each experiment 3 times, just to be sure the data collected is accurate 9. At step 4, replace the underlined compound with the next compound after one experiment is completed Data Recorded Magnesium Ribbon – Mg + 2HCl → MgCl2 + H2 Trial 1 (0.064  ± 0.005 grams) Time (in seconds)  ± 0.05 s Volume (in cm3)  ± 2.5 cm3 Conclusion Unfortunately I was unable to create a graph using time as the independent variable, because the lab that I had utilized did not have the equipment available to accurately to record the data if time were to be the independent variable. Another factor that played into my decision was the fact that the smallest calibration of the glass syringe I used was 5 cm3. Since the only visible measurements shown on the syringe were multiples of 5, it would only seem reasonable that I switch around the variables, making time the dependent variable, and the volume collected the independent variable, since I couldn’t exactly measure how much gas would be collected every 5 seconds; otherwise the relationship the graph would depict would be completely incorrect. As you can see on the graphs, the slightly steep slopes show when the reaction is the quickest, as it should be in the beginning. The curve shows the reaction slowing down, but unfortunately the curve continues. This is because the reaction is still taking place. I was unable to record the rest of the data because the measuring tools that were available weren’t able to record to such a high degree. In some cases though, like in the powdered sodium carbonate experiment, the reaction began so quickly that I wasn’t able to record the time in most cases, so I just stuck with those that I had managed to note down. In other cases, there were so many distractions in the lab that it was difficult to remain focused. My classmates kept removing some if the items that I was using. The idea was to see how the rate of reaction changed when the surface area of a substance was increased. Initially, my plan was to react magnesium ribbon and magnesium powder with 1 mole of Hydrochloric acid; so I could compare and contrast how the surface area of the substance affected the rate of reaction. I had planned to keep everything about the two substances the same. Its element, mass, the amount of Hydrochloric acid I was going to react with it; the only thing different would be its surface area. Unfortunately the Lab didn’t have any available. So I decided to do the same experiment to Calcium Carbonate, this time using marble chips and powdered calcium carbonate. To my dismay I found that the powdered calcium carbonate wasn’t reacting at all. So I had to change it to sodium carbonate. There is skepticism about using different elements, seeing as they have different orders of reactivity. These factors, including the concentration of the acid used, could also affect the rate of reaction. However, the same acid concentration was used for all experiments, in all trials; so we can dismiss that. However, sodium is much higher up the reactivity series than calcium, which is higher up the reactivity series than magnesium. This is the problem with this experiment; the elements positions in the reactivity series could have really altered the rate of reaction. However, the experiments still prove that when the surface area of a substance is increased, the rate of reaction increases as well. This happens because, when two substances react only the surface particles of the substances can come into direct contact with the reactant particles. Increasing a substance’s surface area, like turning big solid chunks of calcium carbonate into powder, leaves more solid particles available to react. The more particles available to react at one time, the faster the rate of the reaction. Like this: Only atoms on the surface can react If you break the substance down, more atoms are exposed and ready to react. Evaluation Considering the lack of material available, I think I was able to manage the experiment fairly enough to produce results. However, I am not pleased with the factors that may or may not have affected my results, and the circumstances in which I had to switch my variables around. Therefore I would like to state a few things I would like to alter, if ever I got the change to do this experiment again. 1. Apparatus 1. Next time, instead of using a stopwatch, I would like to use a digital device, like a laptop for example, that was somehow connected to the glass syringe, which was programmed to record the volume of the gas collected every 5 seconds. This time the graph would turn out the way it should be. 2. Instead of using a measuring cylinder, I would replace it with a burette, as it takes more accurate measurements of liquids. 1. Chemicals Used 1. I would try and used the same element next time; the only difference would be the surface area. For example, if I used magnesium, to study the effects of surface area on the rate of reaction, I would only you magnesium ribbon and magnesium powder. Studying different elements with different reactivity’s would dismiss any data already collected because an element’s position on the reactivity series may also determine the rate of reaction. Use the same element. 1. Amount of People involved in the experiment 1. If I had to do the experiment again, with the same apparatus, I think I would like to have 3 people participating in the collection of data. 1 person would be watching the syringe rise and call out to record whenever it rose, the 2nd person would time it, and the 3rd person would record it. This time, the data may be even more accurate, because no one is taking their eye off the experiment, like I was doing during my experiment just to record data. I feel that altering these aspects of the experiment would increase the level of accuracy, as to get more substantial data to calculate the order of reaction. Unfortunately with the data I have so far, I am unable to derive the concentrations of the substances I had utilized in my experiment. However, as the objective was to investigate whether or not different surface areas affected the rate of the reaction, I think that I have produced enough data to support my theory.

Monday, January 20, 2020

Cival Rights Act 1964 :: essays research papers fc

When the Government Stood Up For Civil Rights "All my life I've been sick and tired, and now I'm just sick and tired of being sick and tired. No one can honestly say Negroes are satisfied. We've only been patient, but how much more patience can we have?" Mrs. Hamer said these words in 1964, a month and a day before the historic Civil Rights Act of 1964 would be signed into law by President Lyndon B. Johnson. She speaks for the mood of a race, a race that for centuries has built the nation of America, literally, with blood, sweat, and passive acceptance. She speaks for black Americans who have been second class citizens in their own home too long. She speaks for the race that would be patient no longer that would be accepting no more. Mrs. Hamer speaks for the African Americans who stood up in the 1950's and refused to sit down. They were the people who led the greatest movement in modern American history - the civil rights movement. It was a movement that would be more than a fragment of history, it was a movement that would become a measure of our lives (Shipler 12). When Martin Luther King Jr. stirred up the conscience of a nation, he gave voice to a long lain dormant morality in America, a voice that the government could no longer ignore. The government finally answered on July 2nd with the Civil Rights Act of 1964. The Civil Rights Act of 1964 is historically significant because it stands as a defining piece of civil rights legislation, being the first time the national government had declared equality for blacks. The civil rights movement was a campaign led by a number of organizations, supported by many individuals, to end discrimination and achieve equality for American Blacks (Mooney 776). The forefront of the struggle came during the 1950's and the 1960's when the feeling of oppression intensified and efforts increased to gain access to public accommodations, increased voting rights, and better educational opportunities (Mooney). Civil rights in America began with the adoption of the 13th, 14th, and 15th amendments to the Constitution, which ended slavery and freed blacks in theory. The Civil Rights Acts of 1866 and 1875 were passed, guaranteeing the rights of blacks in the courts and access to public accommodation. These were, however, declared unconstitutional by the Supreme Court, who decided that the fourteenth did not protect blacks from violation of civil rights, by individuals.

Sunday, January 12, 2020

Human Condition Essay Essay

The human condition is a term which references our complicated existence by highlighting our ongoing ability to adapt and change both our perceptions and values. Through our mental capabilities of both creativity and imagination, humanity is able to achieve a sense of both self-actualisation and liberation, resulting in them acting as the core of our existence where, without them we would become susceptible to the overwhelming flaws of the human condition. Evidencing this are the three texts, ‘Dejection: an Ode’, ‘This Lime Tree Bower my Prison’ and ‘Focus’, which Samuel Coleridge’s â€Å"Dejection: an Ode,† is a poem describing a man’s torment as he attempts to overcome his dispirited state as a result of the loss of a romantic relationship. The poem highlights the importance of creativity within humanity through the persona’s struggle to maintain joyous after the loss of such ability, presenting the fact that without creativity, we would become susceptible to the negative aspects of the world. Beginning the poem using pathetic fallacy, Coleridge relates the persona’s reality to the growing storm, which through describing the â€Å"dull pain† received from his loss, highlights the duality present within our emotions, and hence the idea that we have the ability to experience both love as much as we do despair. The poet again reinforces our vulnerability to reality by using a metaphor to describe how it â€Å"coils around my mind,† presenting the fact that without hope and optimism, reality can hinder our creativity. Describing that he was born with a â€Å"shaping spirit of imagination,† the persona alludes to the idea that humanity maintains the ability to bring about their own happiness, which as a whole, demonstrates to the audience that life can only ever be worth living when we have found our own contentment and joy, as encountered only through our imaginative pursuits. As the poem concludes, the importance of maintaining happiness is reiterated as the persona wishes his lover to rejoice, asking for joy to become the â€Å"eddying of her living soul,† which again expresses the concept of inner contentment, which at times can only be found through creativity, as the core of the human existence. Coleridge’s ‘This Lime Tree Bower My Prison’, is a poem describing a man’s changing views as he contemplates the natural word which he has been prevented from seeing. Coleridge’s poem demonstrates the ability of individuals to modify their morals and values upon receiving a cathartic release from their relationship with nature, as predicated almost entirely on the imagination. Through allowing the persona to visualise the encounters his friends are making with nature along their journey, Coleridge first demonstrates the capabilities of the imagination in allowing us to picture things in certain detail, as shown through â€Å"now my friends emerge,† which in all exemplifies the presence of imagination in our relationship with nature. Furthermore, the description of their journey demonstrates the liberation received from engaging with nature, as shown where they â€Å"wander in gladness,† which relates to the cathartic release obtained from viewing nature that pushes us to reassess our ideas and perceptions. By showing his gradual change in tone, the influence of the persona’s imagination is shown, which when in conjunction with his exclamation of â€Å"yes!† reveals our emotional capabilities if becoming engulfed in our imaginations of nature. Also, by choosing to allow the persona to speak in a melodramatic tone, the poet is able to again explicitly demonstrate his overwhelming feelings from picturing various landscapes, as seen in the alliteration â€Å"silent with swimming sense,† which further reveals nature’s ability to liberate our senses. Similarly, Coleridge’s conclusion to the poem, which involves a reflection of the persona’s realisations as he contemplated the beauty around him, provides a retrospective view of experience and what he â€Å"henceforth shall know,† which ultimately reveals humanity’s capabilities to both adapt and change their morals and values through perceiving new ideas and perceptions. Ari Kruger’s ‘Focus,’ is a 2011 short film depicting the changing perceptions of a young man as he enters and loses a romantic relationship. The film portrays the inevitable presence of flaws within the human existence, while simultaneously recognising the natural beauties that are still present. The concept of being unable to decipher things beyond the obvious is first received by Kruger’s choice to film in black and white, which in conjunction to the man’s struggle to continue to see the positive traits of his partner, highlights humanity’s inability to, at times, see beyond the realm of ‘black and white’ and hence recognise the more ‘colourful’ aspects. The man’s growing blindness over the beauties of his relationship due to an unnamed flaw is successfully conveyed through the use of camera focus to gradually blur the young girl until she is ultimately unrecognisable, which mirrors the consequences of choosing to focus singularly on the imperfections of humanity and overlook the positive attributes. In the shot where the girl looks grumpily along as he uses his computer, the device is seen as a metaphor for the technological advancements or barriers which have hindered his appreciation of all things natural, namely the positive traits of his partner. Parallels with this exist within Coleridge’s ‘This Lime Tree Bower My Prison,’ where the persona is blinded from feeling the beauty of nature by his resentment, describing how it had ‘dimmed mine eyes. ’ The superiority of those who recognise both the beauties and flaws of humanity can be seen through the higher positioning of the girl on the bed as the man sits on the floor, further highlighting the importance for ourselves to similarly do so. Through creating a parallel between the beginning and end of their relationship, Kruger demonstrates that despite the melancholy tones of the last scenes, the man has now achieved liberation by realising his own flaw as the pinnacle of their conflict, which as shown through the repetition of non-diegetic music, allows us to realise the cathartic release we can only achieve from recognising the dichotomised attributes of humanity. Although it is complex, the human condition can be simplified into several key aspects that act as the core of our existence, as outlined in the above texts. It can be seen that through creativity and imagination, humanity is able to reach a sense of self-actualisation which allows them to realise the basic flaws of their existence without overlooking its natural beauty.

Saturday, January 4, 2020

Theme of Isolation in William Faulkners A Rose for Emily...

The Theme of Isolation in A Rose for Emily As an author establishes the characters he simultaneously attempts to develop the theme of the story. An author uses various elements such as point of view, the setting, and symbols to work toward the expression of one central idea. In looking at A Rose for Emily. a short story by William Faulkner, it is evident that Faulkner successfully carries one main idea throughout the piece, the idea of being isolated from society. One of the most effective elements that Faulkner uses in his development of this main idea is the use of imagery. He portrays the father of Emily as a looming possessive figure, a figure of total control and dominance(Gwin 31). Emily has no say about what goes on†¦show more content†¦This reality sends panic and fear through her because now she has nowhere to turn and no one to tell her what to do, no one to command her life. Not only is she stricken with the loss of her father but now she is cut off to the outside world, because her only link has passed on. Emily immediately goes into a state of denial; to her, her father could not be dead, he was all that she had and she would not let him go. The day after his death all the ladies prepared to call at the house and offer their condolence and aid... Miss Emily met them at the door, dressed as usual and with no trace of grief on her face. She told them that her father was not dead. She did that for three days... Just as they were about to resort to law and force, she broke down, and they buried her father quickly (Faulkner page #). Without her father, she had no one to put any order in her life and wasnt going to let anyone else try. We remembered all the young men her father had driven away, and knew with nothing left, she would have to cling to that which robbed her, as people will (Faulkner page #). 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